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Why carboxylic acids are more acidic than alcohols and phenols?

Why carboxylic acids are more acidic than alcohols and phenols?

Carboxylic acids dissociate in water to form carboxylate ion and the hydronium ion. The carboxylate ion formed is stabilized through resonance by effective delocalization of the negative charge. Hence, the carboxylic acids are more acidic than phenols.

Why are carboxylic acids acidic and alcohols most often are not?

The common explanation for why carboxylic acids are more acidic than other molecules (such as alcohols) is that resonance delocalization of charge stabilizes the conjugate base anion relative to the reactant acid.

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Why do carboxylic acids have stronger hydrogen bonding than alcohols?

Carboxylic acids show a high degree of association through hydrogen bonding. We have encountered such bonding previously with alcohols; however, acids form stronger hydrogen bonds than alcohols because their O−H bonds are more strongly polarized as −δ⊖O−δ⊕H.

Why are carboxylic acids more acidic than alcohols or alkanes choose all that apply?

Deprotonation of a carboxylic acid forms a resonance-stabilized conjugate base—a carboxylate anion. A carboxylic acid is a stronger acid than an alcohol or phenol because its conjugate base is most effectively resonance stabilized (Doesn’t depend on number of resonance structures!!!)

Are carboxylic acids weak or strong?

Carboxylic acids are weak acids because they only partially ionise in solution. Their solutions do not contain many hydrogen ions compared to a solution of a strong acid at the same concentration. A weak acid’s pH will be higher than a strong acid’s pH at the same concentration.

Why are carboxylic acids more soluble in water than alcohols?

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Carboxylic acids are more soluble in water than alcohols, ethers, aldehydes, and ketones of comparable molecular weight. They form hydrogen bonds with water molecules through both their C=O. and OH groups.

Why do carboxylic acids have higher boiling points than similar alcohols or aldehydes?

Carboxylic acids have higher boiling points than aldehyde, ketones and even alcohols of comparable molecular mass because of the extent of intermolecular-hydrogen bonding with water, due to which they exist as associated molecules. The hydrogen bonds are not completely broken in the vapour state.

Why are carboxylic acids acidic?

The acidity of the carboxylic acids Using the definition of an acid as a “substance which donates protons (hydrogen ions) to other things”, the carboxylic acids are acidic because of the hydrogen in the -COOH group. In solution in water, a hydrogen ion is transferred from the -COOH group to a water molecule.

Why are mineral acid is stronger acid than carboxylic acid?

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Mineral acids dissociate completely in water and give more H+ ions whereas carboxylic acid does not dissociate easily and give less H+ ions.