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When nitric acid and sulfuric acid mixed What is happening there?

When nitric acid and sulfuric acid mixed What is happening there?

In here, the sulfuric acid overpowers nitric acid, and so nitric acid acts as a Bronsted-Lowry base here, accepting that hydrogen ion, and then decomposing into water (H2O) and a nitronium ion (NO+2) , as H2NO+3(aq) is a really unstable ion.

What is the role of nitric acid in nitration?

HNO3 acts as a base in the nitrating mixture and provides the electrophile NO2+ .

Why is Sulphuric acid the preferred catalyst in the nitration reaction?

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Furthermore, sulphuric acid bonds with water, resulting from the nitration reaction, thus ensuring that practically all of the nitric acid is used for nitration.

Why do you use an ice bath when adding nitric acid to sulfuric acid?

The reaction mixture is poured over ice to precipitate the crude product. Ice is used because the reaction of concentrated acids, especially concentrated sulfuric acid, with water is very exothermic. This would lead to the hydrolysis of the ester function during this step.

Can sulfuric acid and nitric acid be stored together?

Incompatible acids must not be stored together. (Examples: perchloric acid is not to be stored with a reducing agent such as sulfuric acid, as upon mixing, this could produce a shock sensitive explosive; nitric acid and acetic acid, a potential explosive mixture, must not be stored together.)

Why is sulfuric acid add to methyl benzoate?

Nitric and sulfuric acid react to form the nitronium ion electrophile. Nucleophilic π electrons attack the nitronium ion giving methyl 3-nitrobenzoate.

What is the purpose of the nitration of methyl benzoate lab?

The purpose of this reaction it’s to perform a nitration reaction on methyl benzoate to create a product of 3-nitro methyl benzoate. Within a nitration reaction it is typical to see electrophilic aromatic substitution reactions occur. It is important to note the characteristics of an aromatic structure.

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What is the role of sulfuric acid in the nitration of benzene rings?

Sulfuric acid is needed in order for a good electrophile to form. Sulfuric acid protonates nitric acid to form the nitronium ion (water molecule is lost). The nitronium ion is a very good electrophile and is open to attack by benzene. Without sulfuric acid the reaction would not occur.

What is the function of the sulfuric acid in the nitration of bromobenzene?

The sulfuric acid acts as a catalyst, reacting with the nitric acid to produce the nitronium ion, which is the active electrophile in this reaction.

What happens when you mix sulfuric acid and nitric acid?

Sulfuric acid and Nitric acid are mixed in equal volumes (50:50) or 1:1 in a nitration reaction. Sulfuric Acid Activation of Nitric Acid. The first step in the nitration of benzene is to activate HNO3with sulfuric acid to produce a stronger electrophile, the nitronium ion.

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What is the role of sulphuric acid in nitration of benzene?

Nitration in the benzene ring is an electrophilic substitution reaction, and the electrophile involved here is the nitronium ion, NO2+. Sulphuric acid being a stronger acid than nitric acid facilitates easy generation of NO2+ by protonating the latter. Even nitration of benzene is carried out by using this nitration mixture only.

How do you make nitric acid from benzene?

Sulfuric Acid Activation of Nitric Acid. The first step in the nitration of benzene is to activate HNO3with sulfuric acid to produce a stronger electrophile, the nitronium ion. Because the nitronium ion is a good electrophile, it is attacked by benzene to produce Nitrobenzene.

What is nitnitration in the benzene ring?

Nitration in the benzene ring is an electrophilic substitution reaction, and the electrophile involved here is the nitronium ion, NO2+. Sulphuric acid being a stronger acid than nitric acid facilitates easy generation of NO2+ by protonating the latter.