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Can an exothermic process be non-spontaneous?

Can an exothermic process be non-spontaneous?

An exothermic reaction can be non-spontaneous when the temperature is high and entropy is negative, as shown in the ∆G = ∆H-T∆S equation.

Are all endothermic reactions spontaneous?

Most endothermic reactions are non-spontaneous; without a steady supply of energy, the reactions typically come to a stop. However, a spontaneous endothermic reaction can occur when the changes in enthalpy and entropy yield a negative Gibbs free energy.

Are exothermic reactions spontaneous at all temperatures?

Combustion processes are exothermic (ΔH < 0). The reaction is therefore spontaneous (ΔG < 0) at all temperatures.

Why all exothermic reactions are not spontaneous?

All spontaneous processes are not exothermic, because it is the Gibbs Free energy that determines spontaneity, not the enthalpy. You will notice that this expression may be positive even with a negative enthalpy change (exothermic process) if the entropy change is negative and the temperature is high enough.

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How do you tell if a reaction is spontaneous or not?

If ΔH is negative, and –TΔS positive, the reaction will be spontaneous at low temperatures (decreasing the magnitude of the entropy term). If ΔH is positive, and –TΔS negative, the reaction will be spontaneous at high temperatures (increasing the magnitude of the entropy term).

What types of reactions are spontaneous?

A spontaneous reaction is a reaction that favors the formation of products at the conditions under which the reaction is occurring. A roaring bonfire is an example of a spontaneous reaction, since it is exothermic (there is a decrease in the energy of the system as energy is released to the surroundings as heat).

Why do exothermic reactions tend to be spontaneous?

Since the energy of the system decreases during an exothermic reaction, the products of the system are more stable than the reactants. However, endothermic reactions do occur spontaneously, or naturally. There must be another driving force besides enthalpy change which helps promote spontaneous chemical reaction.

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How do you know if a reaction is spontaneous?

When a reaction is non spontaneous?

A nonspontaneous reaction is a reaction that does not favor the formation of products at the given set of conditions. In order for a reaction to be nonspontaneous, it must be endothermic, accompanied by a decrease in entropy, or both. Our atmosphere is composed primarily of a mixture of nitrogen and oxygen gases.

Which type of reaction is always spontaneous?

Exothermic reactions are always spontaneous. Endothermic reactions are never spontaneous. Endothermic reactions are never spontaneous. A reaction that leads to an increase in the entropy of the system is always spontaneous.

How do you know if a reaction is spontaneous or not?

What type of reaction does not happen spontaneously?

The reverse reaction, as written above, is not spontaneous.

Are all spontaneous processes exothermic?

Generally, all spontaneous processes are not exothermic, since the Gibbs Free energy that determines spontaneity, not the enthalpy. Any process is said to be spontaneous if the Gibbs free energy is negative.

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Are all reactions exothermic at standard state?

No, but all reactions that are spontaneous at standard state (interpreted to mean that at standard state, equilibrium lies in the forward direction, i.e. K > 1 and $\\Delta_r G^\\circ < 0$) are either exothermic ($\\Delta_r H^\\circ < 0$) or show a positive standard entropy of reaction ($\\Delta_r S^\\circ > 0$), or both.

What are the conditions under which a chemical reaction is spontaneous?

All the reactants are mono-atomic gases, and the product is a solid. This is a strong indication that the entropy of the system decreases. The reaction is spontaneous That statement from the text of the question means that the Gibbs energy of reaction is negative. It is not clear if this refers to standard conditions, or to the current conditions.